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prunasin and amygdalin biosynthesis

State Icon Reaction EC-Number Confidence maximal confidence score from EnzymeDetector
L-phenylalanine + O2 + reduced_[NADPH-hemoprotein_reductase] <=> N-hydroxy-L-phenylalanine + oxidized_[NADPH-hemoprotein_reductase] + H2O + H+ not assigned

N-hydroxy-L-phenylalanine + O2 + reduced_[NADPH-hemoprotein_reductase] <=> N,N-dihydroxy-L-phenylalanine + oxidized_[NADPH-hemoprotein_reductase] + H2O not assigned

phenylacetonitrile + O2 + reduced_[NADPH-hemoprotein_reductase] <=> (R)-mandelonitrile + H2O + oxidized_[NADPH-hemoprotein_reductase] 1.14.14.77 phenylacetonitrile alpha-monooxygenase

UDP-glucose + (R)-mandelonitrile <=> prunasin + UDP + H+ 2.4.1.178 hydroxymandelonitrile glucosyltransferase
2.4.1.354 (R)-mandelonitrile beta-glucosyltransferase
2.4.1.85 cyanohydrin beta-glucosyltransferase



(E)-phenylacetaldoxime <=> (Z)-phenylacetaldoxime 1.14.14.44 phenylacetaldehyde oxime monooxygenase

UDP-glucose + prunasin <=> amygdalin + UDP + H+ 2.4.1

N,N-dihydroxy-L-phenylalanine + H+ <=> (E)-phenylacetaldoxime + CO2 + H2O 1.14.14.40 phenylalanine N-monooxygenase

(Z)-phenylacetaldoxime <=> phenylacetonitrile + H2O 1.14.14.44 phenylacetaldehyde oxime monooxygenase
4.99.1.5 aliphatic aldoxime dehydratase
4.99.1.7 phenylacetaldoxime dehydratase



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