|
|
L-phenylalanine + O2 + reduced_[NADPH-hemoprotein_reductase] <=> N-hydroxy-L-phenylalanine + oxidized_[NADPH-hemoprotein_reductase] + H2O + H+
|
not assigned
|
–
|
|
MetaCyc:
RXN-12066
|
|
|
|
N-hydroxy-L-phenylalanine + O2 + reduced_[NADPH-hemoprotein_reductase] <=> N,N-dihydroxy-L-phenylalanine + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
not assigned
|
–
|
|
MetaCyc:
RXN-12067
|
|
|
|
phenylacetonitrile + O2 + reduced_[NADPH-hemoprotein_reductase] <=> (R)-mandelonitrile + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
1.14.14.77
phenylacetonitrile alpha-monooxygenase
|
–
|
|
MetaCyc:
RXN-18098
|
|
|
|
UDP-glucose + (R)-mandelonitrile <=> prunasin + UDP + H+
|
2.4.1.178
hydroxymandelonitrile glucosyltransferase
2.4.1.354
(R)-mandelonitrile beta-glucosyltransferase
2.4.1.85
cyanohydrin beta-glucosyltransferase
|
–
–
–
|
|
BRENDA:
BR52384;
BS356146
KEGG:
R10638
MetaCyc:
RXN-18095
|
|
|
|
(E)-phenylacetaldoxime <=> (Z)-phenylacetaldoxime
|
1.14.14.44
phenylacetaldehyde oxime monooxygenase
|
–
|
|
BRENDA:
BR52033
KEGG:
R10041
MetaCyc:
RXN-12065
|
|
|
|
UDP-glucose + prunasin <=> amygdalin + UDP + H+
|
2.4.1
|
–
|
|
KEGG:
R10639
MetaCyc:
RXN-18094
|
|
|
|
N,N-dihydroxy-L-phenylalanine + H+ <=> (E)-phenylacetaldoxime + CO2 + H2O
|
1.14.14.40
phenylalanine N-monooxygenase
|
–
|
|
BRENDA:
BR49592
KEGG:
R09581
MetaCyc:
RXN-12068
|
|
|
|
(Z)-phenylacetaldoxime <=> phenylacetonitrile + H2O
|
1.14.14.44
phenylacetaldehyde oxime monooxygenase
4.99.1.5
aliphatic aldoxime dehydratase
4.99.1.7
phenylacetaldoxime dehydratase
|
–
–
–
|
|
BRENDA:
BR48646
KEGG:
R07638
MetaCyc:
4.99.1.7-RXN
SABIO-RK:
6866
|
|